Radical Desalination Approach May Disrupt the Water Industry

Currently, hypersaline brines are desalinated either by membrane (reverse osmosis) or water evaporation (distillation). Each approach has limitations. Reverse osmosis methods are ineffective for high-saline brines because the pressures applied in reverse osmosis scale with the amount of salt: hypersaline brines require prohibitively high pressurizations. Distillation techniques, which evaporate the brine, are very energy-intensive.

Yip has been working on solvent extraction, a separation method widely employed for chemical engineering processes. The relatively inexpensive, simple, and effective separation technique is used in a wide range of industries, including production of fine organic compounds, purification of natural products, and extraction of valuable metal complexes.

“I thought solvent extraction could be a good alternative desalination approach that is radically different from conventional methods because it is membrane-less and not based on evaporative phase-change,” Yip says. “Our results show that TSSE could be a disruptive technology—it’s effective, efficient, scalable, and can be sustainably powered.”

TSSE utilizes a low-polarity solvent with temperature-dependent water solubility for the selective extraction of water over salt from saline feeds. Because it is membrane-less and not based on evaporation of water, it can sidestep the technical constraints that limit the more traditional methods. Importantly, TSSE is powered by low-grade heat (50%) for the hypersaline brines, also comparable to current seawater desalination operations. But, unlike TSSE, reverse osmosis cannot handle hypersaline brines.

“We think TSSE will be transformational for the water industry. It can displace the prevailing practice of costly distillation for desalination of high-salinity brines and tackle higher salinities that RO cannot handle,” Yip adds. “This will radically improve the sustainability in the treatment of produced water, inland desalination concentrate, landfill leachate, and other hypersaline streams of emerging importance. We can eliminate the pollution problems from these brines and create cleaner, more useable water for our planet.”

Yip’s TSSE approach has a clear path to commercialization. The heat input can be sustainably supplied by low-grade thermal sources such as industrial waste heat, shallow-well geothermal, and low-concentration solar collectors. He is now working on further refining how TSSE works as a desalination method so that he can engineer further improvements in performance and test it with real-world samples in the field.

 Contacts and sources:Holly Evarts
Columbia University School of Engineering and Applied Science
Citation: Membrane-less and Non-evaporative Desalination of Hypersaline Brines by Temperature Swing Solvent Extraction.
Chanhee Boo, Robert K. Winton, Kelly M. Conway, Ngai Yin Yip. Environmental Science & Technology Letters, 2019; DOI: 10.1021/acs.estlett.9b00182