Progress On The Solid State Lithium Ion Battery

Tokyo Institute of Technology scientists have addressed one of the major disadvantages of all-solid-state batteries by developing batteries with a low resistance at their electrode/solid electrolyte interface.

The fabricated batteries showed excellent electrochemical properties that greatly surpass those of traditional and ubiquitous Li-ion batteries; thereby, demonstrating the promise of all-solid-state battery technology and its potential to revolutionize portable electronics.

Most consumers are familiar with rechargeable lithium ion batteries, which have been developing over the last few decades, and are now common in all sorts of electronic devices. Despite their broad use, scientists and engineers believe that traditional Li-ion battery technology is already nearing its full potential and new types of batteries are needed.

The team described their work in a paper published in ACS Applied Materials & Interfaces.

All-solid-state batteries are a new type of Li-ion battery, and have been shown to be potentially safer and more stable energy-storing devices with higher energy densities. However, the use of such batteries is limited due to a major disadvantage: their resistance at the electrode/solid electrolyte interface is too high, hindering fast charging and discharging.

Scientists from Tokyo Institute of Technology and Tohoku University, led by Professor Taro Hitosugi, fabricated all-solid-state batteries with extremely low interface resistance using Li(Ni_0.5Mn_1.5)O₄ (LNMO), by fabricating and measuring their batteries under ultrahigh vacuum conditions, ensuring that the electrolyte/electrode interfaces were free of impurities.

After fabrication, the electrochemical properties of these batteries were characterized to shed light on Li-ion distribution around the interface. X-ray diffraction and Raman spectroscopy were used for analyzing the crystal structure of the thin films comprising the batteries.

Spontaneous migration of Li ions was found to occur from the Li3PO4 layer to the LNMO layer, converting half the LNMO to L₂NMO at the Li₃PO₄/LNMO interface. The reverse migration occurs during the initial charging process to regenerate LNMO.

The resistance of this interface, verified using electrochemical impedance spectroscopy, was 7.6 Ω cm², two orders of magnitude smaller than that of previous LMNO-based all-solid-state batteries and even smaller than that of liquid-electrolyte-based Li-ion batteries using LNMO. These batteries also displayed fast charging and discharging, managing to charge/discharge half the battery within just one second.

Moreover, the cyclability of the battery was also excellent, showing no degradation in performance even after 100 charge/discharge cycles.

Li(Ni_0.5Mn_1.5)O₄ is a promising material to increase the energy density of a battery, because the material provides a higher voltage. The research team hopes that these results will facilitate the development of high-performance all-solid-state batteries, which could revolutionize modern portable electronic devices and electric cars.

Batteries seem to generate the most news and press releases and for many the progress seems slow. But the little incremental improvements are seldom if ever announced in product releases to consumes.

But when solid state lithium ion comes to market you’re sure to see a blurb on the packaging. And it will be a much higher capacity longer lasting battery.